ARM U™ 28% NBPT

A liquid fertiliser additive that controls ammonia volatilisation from urea and urea ammonium nitrate (UAN) fertilisers.

Description

ARM U™ 28% NBPT is an NBPT based fertiliser additive that allows plants to absorb and utilise nitrogen efficiently, which otherwise disappears too quickly through conversion to ammonia gas.

When to Use

Whenever urea or UAN fertiliser is applied to soil.

Benefits

Best for High Nitrogen Loss Situations
Effective in high pH soils and low moisture conditions.

Inhibits NH3 Loss
Reduces ammonia volatilisation by up to 92% compared to untreated urea.

Maximises Fertiliser Efficiency
Minimises nitrogen loss, boosts fertiliser efficiency, and reduces costs.

Effortless Application
The liquid formulation allows for easy application with thorough coverage and minimal handling issues.

Consistent Performance
Reliable performance across a wider range of environmental conditions.

Add DMPP for Dual Protection
Can be mixed with ARM U™ 16% DMPP to inhibit all forms of nitrogen loss.

How it Works

Nitrogen is essential for plant life and growth and is therefore a component of many fertilisers. However, up to 50% of the nitrogen applied as soil fertiliser is unavailable to plants because it is quickly converted to ammonia gas and released into the atmosphere. ARM U 28% NBPT inhibits this enzymatic process, allowing nitrogen to be absorbed through the plant roots.

Unlike other NBPT formulations, ARM U 28% NBPT is patented and an improved formulation that contains polymers (spreader molecules) that increase NBPT’s binding rates to urease enzyme leading to improved NBPT activity. This increased activity enables a lower active ingredient and a lower use rate. In addition, ARM U 28% NBPT is formulated to have a high buffering capacity to keep the solution pH below 7 and to protect and fully utilise the nitrogen present in the NBPT molecule.

While Active AgriScience stands behind the quality of our products (see guarantee below), Active AgriScience cannot guarantee the same, or similar, yield results due the effects of variables outside of our control (soil conditions, weather, pests, diseases, tank mix partners, application rates, and errors in mixing and application). We encourage all prospective customers to run trials of our products before broad acreage adoption.

Active AgriScience 100% guarantees the quality of its products with a 15-month free replace warranty*. To aid consumers to make informed purchasing decisions all Yield Data posted on our Website and App is from Certified 3rd Party Tests.

*Improper use and/or storage, as per label instructions, voids the warranty. Product must be stored out of direct sun light within a temperature range of 5 – 35°C. Warranty is limited to the cost of the product and may be satisfied by free replacement of defective product, a credit note or refund (at the discretion of Active AgriScience Inc).

Label

28% NBPT

UREASE INHIBITOR

ACTIVE INGREDIENT: 28.3% N-(n-butyl) thiophosphoric triamide (NBPT).
INACTIVE INGREDIENTS: (71.7%) [N-methyl-2-pyrrolidone (NMP), propylene glycol, emulsifier, preservative, dye] READ THE ENTIRE LABEL BEFORE USING THIS PRODUCT.
BLENDING INSTRUCTIONS:
Blending into UREA: Use 2 L ARM U™/1000 kg Urea. For uniform blending, use a blender with impregnation equipment. Weigh the urea and transfer to blender. Add the required amount of ARM U™ 28% NBPT to the urea in the blender. Blend until the ARM U™ 28% NBPT is uniformly mixed into the urea. Do not add any other fertiliser materials until ARM U™ 28% NBPT is thoroughly distributed. If mixture appears wet or sticky, a drying agent may be added at this time.
Blending into UREA-AMMONIUM NITRATE (UAN) SOLUTIONS: Use 1.2 L ARM U™ 28% NBPT / 1000 kg UAN solution. Fill spray tank with half the desired amount of UAN, Measure the recommended quantity of ARM U™ 28% NBPT and add to the tank. Mix well. Add other products at this stage, if needed. Add the second half of the UAN solution. Continue mixing until well blended.
NOTE: Density=1.1 grams / cubic centimeter at 20°C.

ANALYSIS (W/V):

  • N-(n-butyl) thiophosphoric triamide (NBPT): 28.3%
WHMIS Pictogram Health HazardWHMIS Pictogram ExclamationWHMIS Pictogram Corrosive

DANGER HAZARD STATEMENTS:CAUSES SERIOUS EYE DAMAGE. CAUSES SKIN IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. MAY DAMAGE FERTILITY OR THE UNBORN CHILD.


PRECAUTIONARY STATEMENTS: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear chemical resistant gloves, coveralls, goggles and face protection. Change gloves frequently. Wear air supplied respirator where airborne concentrations exceed recommended exposure limits or are unknown. Do not eat, drink or smoke when using this product. Wash up thoroughly before eating, drinking, smoking and leaving work. Keep livestock off treated areas until after 14 days or 2.5 cm of rainfall has accumulated.
FIRST AID: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE / doctor. IF ON SKIN: Immediately take off all contaminated clothing. Rinse skin with water (or shower). Wash contaminated clothing before reuse. Seek immediate medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTRE / doctor. IF IN EYES: Immediately flush eyes with a gentle stream of water for 15 minutes while holding the upper and lower eyelids open. Remove contact lenses, if present and easy to do. Seek immediate medical attention.
STORAGE: KEEP OUT OF REACH OF CHILDREN. Store locked up in a cool, dry, well ventilated area away from food or feed storage. DO NOT FREEZE.
DISPOSAL: Dispose of this product and its container in accordance with Federal, Provincial, and Local regulations.
WARRANTY AND CONDITIONS OF SALE: Manufacturer warrants that this material conforms to the chemical description hereon and is reasonably fit for use as directed. No other warranty is made, either expressed or implied.
FOR CHEMICAL EMERGENCY: Call +1800 039 008 or refer to SDS.

made in australia

For product inquiries visit activeagriscience.com.
Formulated and manufactured in Australia.

Active AgriScience Inc. DISCLAIMER: Please read this limitation carefully as it impacts your legal rights. It is understood and agreed that Active AgriScience Inc. (“Active”) does not guarantee that use of this Product will yield any specific results. Active’s legal liability, and that of its employees or agents, arising from use of this product shall be limited to the cost paid for the product regardless of whether any loss arose from Active’s own negligence or breach of contract or any other cause. Under no circumstances shall Active be liable, beyond the cost paid for the product, for direct, consequential, incidental, or special damages, including, but not limited to, damage or destruction of a crop, reduced yield from any crop, or contamination of any property. Use or sale of this product confirms acceptance of this limitation of legal liability.

Compatibility

Compatible with urea, urea ammonium nitrate and other urea based fertilizers.

Safety Data Sheet

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT IDENTIFIER

ARM U 28% NBPT

PRODUCT USE

Liquid nitrogen stabiliser for urea fertilisers

MANFACTURERS NAME

Active Agriscience Australia Pty Ltd.

DATE

Oct. 4, 2024

EMERGENCY TELEPHONE

+1800 039 008

PREPARED BY

Active Agriscience Australia Pty Ltd.

USE RESTRICTIONS

For professional use only. Use only as labeled.

DISTRIBUTORS NAME

 

STREET ADDRESS

 

CITY

 

POSTAL CODE

 

COUNTRY

 

EMERGENCY TELEPHONE

 

 

SECTION 2 – HAZARDS IDENTIFICATION

GHS CLASSIFICATION

HPR (WHMIS 2015)

Eye Damage / Irritation: Category 1

Skin Corrosion / Irritation: Category 2

Specific Target Organ Toxicity (STOT); Single exposure: Category 3 (respiratory irritation)

Specific Target Organ Toxicity (STOT); Single exposure: Category 2 (kidneys)

Reproductive toxicity: Category 1B

OSHA Hazard Communication Standard (29 CFR 1910.1200)

Eye Damage / Irritation: Category 1

Skin Corrosion / Irritation: Category 2

Specific Target Organ Toxicity (STOT); Single exposure: Category 3 (respiratory irritation)

Specific Target Organ Toxicity (STOT); Single exposure: Category 2 (kidneys)

Reproductive toxicity: Category 1B

WHMIS Pictogram Health Hazard

WHMIS Pictogram Exclamation

WHMIS Pictogram Corrosive

DANGER

HAZARD STATEMENTS: CAUSES SERIOUS EYE DAMAGE. CAUSES SKIN IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. MAY DAMAGE FERTILITY OR THE UNBORN CHILD.

PRECAUTIONARY STATEMENTS: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear chemical resistant gloves, coveralls, goggles and face protection. Change gloves frequently. Wear air supplied respirator where airborne concentrations exceed recommended exposure limits or are unknown. Do not eat, drink or smoke when using this product. Wash up thoroughly before eating, drinking, smoking and leaving work. Keep livestock off treated areas until after 14 days or 2.5 cm of rainfall has accumulated.

FIRST AID: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE / doctor. IF ON SKIN: Immediately take off all contaminated clothing. Rinse skin with water (or shower). Wash contaminated clothing before reuse. Seek immediate medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.  Immediately call a POISON CENTRE / doctor. IF IN EYES: Immediately flush eyes with a gentle stream of water for 15 minutes while holding the upper and lower eyelids open. Remove contact lenses, if present and easy to do. Seek immediate medical attention.

STORAGE: KEEP OUT OF REACH OF CHILDREN. Store locked up in a cool, dry, well-ventilated area away from food or feed storage. DO NOT FREEZE.

DISPOSAL:
Dispose of this product and its container in accordance with Federal, Provincial, and Local regulations.

 

 

SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS

INGREDIENTS

CAS#

CONCENTRATION

1-Methyl-2-pyrrolidone

872-50-4

5-10%

Ethylene glycol

107-21-1

20-30%

Propylene glycol (propane-1,2-diol)

57-55-6

20-30%

Butyl phosphorothioic triamide

94317-64-3

26%

Additive(s)

N/A

Remainder %

 

SECTION 4 – FIRST AID MEASURES

EYE CONTACT

Immediately flush eyes with a gentle stream of water for 15 minutes while holding the upper and lower eyelids open. Remove contact lenses, if present and easy to do. Seek immediate medical attention.

SKIN CONTACT

Immediately take off all contaminated clothing. Rinse skin with water (or shower). Wash contaminated clothing before reuse. Seek immediate medical attention.

INHALATION

Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTRE / doctor.

INGESTION

Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE/doctor.

Most Important Symptoms, both acute & delayed

Causes serious eye damage. Causes skin irritation. May cause respiratory irritation. May damage fertility or the unborn child.

 

SECTION 5 – FIRE FIGHTING MEASURES

FLAMMABLE

Product will not burn or support combustion.

MEANS OF EXTINCTION

Use extinguishing methods appropriate for the surrounding fire.

FLASHPOINT & METHOD

NAV

UPPER FLAMMABLE LIMIT

NAV

LOWER FLAMMABILITY LIMIT

NAV

AUTO IGNITION TEMPERATURE

NAV

SENSITIVITY TO IMPACT

NAV

SENSITIVITY TO STATIC DISCHARGE

NAV

HAZARDOUS COMBUSTION PRODUCTS

Toxic irritating and/or corrosive gases may be released during a fire: carbon oxides, nitrogen oxides, sulphur oxides.

 

SECTION 6 – ACCIDENTAL RELEASE MEASURES

LEAK & SPILL PROCEDURES

Wear personal protective equipment outlined in SECTION 8. Ventilate area of spill. Avoid breathing mists. Contain spill then adsorb with inert material and place ­into suitable clean containers for later disposal. Do not release into drains or the environment.

 

SECTION 7 – HANDLING AND STORAGE

HANDLING

Do not handle until all safety precautions have been read and understood. Do not breathe mist/spray. Do not get in eyes, or skin. Wear personal protective equipment outlined in SECTION 8. Wash hands and other exposed areas before eating, drinking, smoking and when leaving work.

STORAGE

KEEP OUT OF REACH OF CHILDREN. Store locked up in a cool, dry, well-ventilated area away from food or feed storage. DO NOT FREEZE.

 

SECTION 8 – EXPOSURE CONTROL / PERSONAL PROTECTION

EXPOSURE STANDARDS

INGREDIENT

REFERENCE

1-Methyl-2-pyrrolidone

SWA [AUS]

TWA: 25 ppm, 103 mg/m³, STEL: 75 ppm, 309 mg/m³

1-Methyl-2-pyrrolidone

SWA [Proposed]

TWA: 20 ppm, 80 mg/m³

Ethylene glycol (particulate)

SWA [AUS]

TWA: — ppm, 10 mg/m³

Ethylene glycol (particulate)

SWA [Proposed]

STEL: — ppm, 10 mg/m³

Ethylene glycol (vapour)

SWA [AUS]

TWA: 20 ppm, 52 mg/m³, STEL: 40 ppm, 104 mg/m³

Propane-1,2-diol (particulates only)

SWA [AUS]

TWA: — ppm, 10 mg/m³

Propane-1,2-diol (total vapour & particulates)

SWA [AUS]

TWA: 150 ppm, 474 mg/m³

Propane-1,2-diol (total vapour & particulates)

SWA [Proposed]

TWA: — ppm, 50 mg/m³

BIOLOGICAL LIMITS

INGREDIENT

REFERENCE

1-Methyl-2-pyrrolidone

Determinant:
5-hydroxy-N-methyl-2-pyrrolidone in urine

Sampling Time: End of shift

BEI: 100 mg/L

ENGINEERING CONTROLS

Avoid inhalation. Use in well-ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended.

PERSONAL PROTECTIVE EQUIPMENT

Skin

Wear chemical resistant gloves, coveralls and face protection when handling or applying this product. Change gloves frequently.

Eyes

Wear chemical resistant goggles when handling or applying this product.

Respirator

Wear air supplied respirator where airborne concentrations exceed recommended exposure limits or are unknown.

 

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

Liquid

COLOUR

Blue

BOILING POINT

NAV

EVAPORATION RATE

NAV

ODOUR

Slight odour

SOLUBILITY IN WATER

Soluble

APPEARANCE

Blue liquid

VISCOSITY

42 cPs at 10°C

FREEZING POINT

NAV

SPECIFIC GRAVITY

1.09-1.15kg/1L

pH

5.9-6.5

ODOUR THRESHHOLD

NAV

 

SECTION 10 – STABILITY AND REACTIVITY

CHEMICAL STABILITY

Stable under normal conditions of use and storage.

INCOMPATIBLE WITH OTHER SUBSTANCES

Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), reducing agents (e.g. sulphites), heat and ignition sources.

HAZARDOUS DECOMPOSING PRODUCTS

May evolve toxic gases (carbon/ nitrogen/ sulphur oxides, hydrocarbons) when heated to decomposition.

 

SECTION 11 – TOXICOLOGICAL INFORMATION

ACUTE TOXICITY

Animal evidence indicates that 1-methyl-pyrrolidone exhibits low acute oral, dermal or inhalation toxicity.

1-Methyl-2-pyrrolidone

  • Oral LD50: 4,150 mg/kg (rat)
  • Dermal LD50: > 5,000 mg/kg (rat)
  • Inhalation LC50: > 5.1 mg/l/4hrs (rat)

Ethylene Glycol (1,2-Ethanediol)

  • Oral LD50: 1670 mg/kg (cat); > 2000 mg/kg (rat)
  • Dermal LD50: 9530 mg/kg (rabbit)
  • Inhalation LC50: 10876 mg/kg (rat)

Propylene Glycol (Propane-1,2-diol)

  • Oral LD50: > 2080 mg/kg (quail)
  • Dermal LD50: 20800 mg/kg (rabbit)

CHRONIC TOXICITY

Based on the available information, product does not meet criteria for chronic toxicity.

EYE / SKIN IRRITATION

Causes serious eye damage and skin irritation.

SENSITIZATION

Not available.

CARCINOGENICITY

No component of this product present at levels ≥ 0.1% is identified as a probable, possible, or confirmed human carcinogen by IARC, or ACGIH.

REPRODUCTIVE TOXICITY

1-Methyl-2-pyrrolidone is classified as damaging the unborn child. Developmental effects, including post implantation loss,foetal malformations and pup mortality, have been observed in rats, rabbits and mice following oral and/or dermal exposure (AICIS). N-(n-Butyl) thiophosphoric triamide is suspected of damaging fertility.

MUTAGENICITY

Based on the available in vitro and in vivo genotoxicity studies the chemical is not considered to be genotoxic.

STOT – SINGLE EXPOSURE

Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in breathing difficulties.

STOT – REPEATED EXPOSURE

Not classified as causing organ damage from repeated exposure.

ASPIRATION

Not classified as causing aspiration.

Possible delayed effects

N-methyl-2-pyrrolidone: effects may be delayed. Animal studies show adverse effects to liver and kidneys.

 

SECTION 12 – ECOLOGICAL INFORMATION

ECO TOXICITY

Aquatic Toxicity

N-(n-butyl)-thiophosphoric triamide

Acute Toxicity

Algea

Crustacea

 

Fish

Test

EC50

EC50

LC50

LC50

Species

Selenastrum capricornutum

Daphnia magna

Daphnia

Lepomis macrochirus

Test Results

280 mg/l, 96 hours

290 mg/l, 48 hours

350 mg/l, 48 hours

1140 mg/l, 96 hours

N-methyl-2-pyrrolidone (CAS 872-50-4)

Acute Toxicity

Crustacea

Algae

Crustacea

Fish

Test

LC50

EC50

EC50

LC50

Species

Palaemonetes vulgaris

Scenedesmus subspicatus

Daphnia magna

Oncorhynchus mykiss

Test Results

1107 mg/l, 96 hours

> 500 mg/l, 72 hours

> 1000 mg/l, 24 hours

> 500 mg/l, 96 hours

Chronic Toxicity

Crustacea

Test

LC50

Species

Daphnia magna

Test Results

25 mg/l, 21 days

Propylene Glycol (CAS 57-55-6)

Acute Toxicity

Crustacea

Test

LC50

Species

Ceriodaphnia

Test Results

18340 mg/l, 48 hours

Ethylene Glycol (CAS 107-21-1)

Acute Toxicity

Fish

Crustacea

Algae

Test

LC50

EC50

ErC50

Species

fish

daphnia magna

algae

Test Results

>72.860 mg/l, 96 hours

>100 mg/l, 48 hours

<13.000 mg/l, 96 hours

Chronic Toxicity

 

 

 

Test

LC50

EC50

NOEC

Species

aquatic invertebrates

aquatic invertebrates

aquatic invertebrates

Test Results

>1.500 mg/l, 28 days

>15.000 mg/l, 21 days

≥1.000 mg/l, 23 days

Persistence and Degradability

This product is not readily biodegradable.

Bioaccumulation potential

Not available.

Partition coefficient n-octanol / water (log Kow)

N-methyl-2-pyrrolidone (CAS 872-50-4)

-0.54

Propylene Glycol (CAS 57-55-6)

-0.92

Ethylene Glycol (CAS 107-21-1)

-1.36

Mobility in soil

Product is water soluble and may move through soil.

 

SECTION 13 – DISPOSAL CONSIDERATIONS

WASTE DISPOSAL

For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Contact the manufacturer/supplier for additional information if disposing of large quantities (if required). Prevent contamination of drains and waterways as aquatic life may be threatened and environmental damage may result.

LEGISTLATION

Dispose of in accordance with relevant local legislation.

 

SECTION 14 – TRANSPORT INFORMATION

SHIPPING

Not classified as a dangerous good by the criteria of the ADG code, IMDG or IATA

 

SECTION 15 – REGULATORY INFORMATION

POISON SCHEDULE

Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).

CLASSIFICATIONS

Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals (GHS Revision 7).

INVENTORY LISTINGS

AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)

All components are listed on AIIC or are exempt.

CANADA: DSL (Canadian Domestic Substances List)

All components are listed on the DSL or are exempt.

UNITED STATES: TSCA (US Toxic Substances Control Act)

All components are listed on the TSCA inventory or are exempt.

 

SECTION 16 – OTHER INFORMATION

ADDITIONAL INFORMATION

WORK PRACTICES – SOLVENTS: Organic solvents may present both a health and flammability hazard. It is recommended that engineering controls should be adopted to reduce exposure where practicable (for example, if using indoors, ensure explosion-proof extraction ventilation is available). Flammable or combustible liquids with explosive limits have the potential for ignition from static discharge. Refer to AS 1020 (The control of undesirable static electricity) and AS 1940 (The storage and handling of flammable and combustible liquids) for control procedures.

RESPIRATORS: In general, the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn, ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air-powered or air-supplied respirators should be considered where prolonged or repeated use is necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration, and the availability of engineering controls should be considered before final selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used; and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

ABBREVIATIONS

ACGIH: American Conference of Governmental Industrial Hygienists
CAS #: Chemical Abstract Service number – used to uniquely identify chemical compounds
CNS: Central Nervous System
EC No.: EC No – European Community Number
EMS: Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)
GHS: Globally Harmonized System
GTEPG: Group Text Emergency Procedure Guide
IARC: International Agency for Research on Cancer
LC50: Lethal Concentration, 50% / Median Lethal Concentration
LD50: Lethal Dose, 50% / Median Lethal Dose
mg/m³: Milligrams per Cubic Metre
OEL: Occupational Exposure Limit
pH: Relates to hydrogen ion concentration using a scale of 0 (highly acidic) to 14 (highly alkaline)
Ppm: Parts Per Million
STEL: Short-Term Exposure Limit
STOT-RE: Specific Target Organ Toxicity (Repeated Exposure)
STOT-SE: Specific Target Organ Toxicity (Single Exposure)
SUSMP: Standard for the Uniform Scheduling of Medicines and Poisons
SWA: Safe Work Australia
TLV: Threshold Limit Value
TWA: Time Weighted Average

 

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